Ammonium exchange capacity of the Xerovouni zeolitic tuffs, Avdella area, Evros Prefecture, Greece

E. Tzamos, N. Kantiranis, G. Papastergios, D. Vogiatzis, A. Filippidis, and C. Sikalidis

Ammonium exchange capacity of the Xerovouni zeolitic tuffs, Avdella area, Evros Prefecture, Greece
Published online 13 May 2011
Clay Minerals 2011 46: 179-187

Zeolitic tuffs from the Xerovouni location of the Avdella area (Evros Prefecture, Greece) contain on average 54 wt.% HEU-type zeolite, 6 wt.% smectite, 4 wt.% mica (64 wt.% microporous minerals), 8 wt.% alkali feldspar, 9 wt.% plagioclase, 11 wt.% cristobalite and 8 wt.% quartz (36 wt.% non-microporous minerals). The chemical formula of the HEU-type zeolite is Ca_2.4K_0.6Na_0.4Mg_0.3Al_6.7Si_29.3O₇₂·17H₂O and the tuffs contain on average 72.3 wt.% SiO₂, 11.9 wt.% Al₂O₃, 1.2 wt.% Fe₂O₃, 1.0 wt.% MgO, 2.8 wt.% CaO, 1.3 wt.% Na₂Oand 1.9 wt.% K₂O. The zeolitic tuffs show an average ammonium exchange capacity of 144 meq/100 g. HEU-type zeolite accounts for the most of the ammonium exchange capacity, while smectite and mica contribute to a relatively small extent. The ammonium exchange capacity of the Xerovouni zeolitic tuffs showed positive correlations with (a) the HEU-type zeolite content, (b) the total microporous minerals content, (c) the loss on ignition content and (d) the CaO content. Such materials could be used in a large variety of agricultural, aquacultural, industrial and environmental applications.